Detalles de publicación
PP 012024
On the Radical Cation Spectra of Fullerenes and Fulleranes. Part 1: C60, C70,C76, C78 and C84
1Istituto Nazionale di Astrofisica – Osservatorio Astrofisica di Catania,
Catania, Italy
2Actinium Chemical Research, Rome, Italy
3Instituto de Astrofisica de Canarias, Tenerife, Spain
4Universidad de La Laguna, Tenerife, Spain
5Consejo Superior de Investigaciones Cientificas, Spain
The radical cation of the fullerene series C60, C70,C76, C78 and C84 were generated in
oleum (fuming sulphuric acid with 30% free SO3) and analyzed by electronic absorption spectroscopy. A general agreement was found between the fullerenes radical cation
spectra generated in oleum and those described in the literature and produced in other conditions. An attempt to correlate the radical cation transition of C60, C70, C76, C78 and C84 in oleum with their ionization potential was proposed.
oleum (fuming sulphuric acid with 30% free SO3) and analyzed by electronic absorption spectroscopy. A general agreement was found between the fullerenes radical cation
spectra generated in oleum and those described in the literature and produced in other conditions. An attempt to correlate the radical cation transition of C60, C70, C76, C78 and C84 in oleum with their ionization potential was proposed.